Gasification & Catalysis

Gasification & Catalysis

Mandate:

This group aims to provide necessary input in the fields of value addition, gasification and liquefaction of coal. This includes direct sourcing of coal for value added products including futuristic advanced carbon nanomaterials. R & D on gasification of high ash coal, biomass, petcoke and to address the industrial problem related to gasification. This research group also provides basic & applied research related to the catalyst and process development for synthetic oils and chemicals production from syngas generated from coal/natural gas/biomass feed stocks.

Section 1: Gasification Methanol and Hydrogen Economy

Important Achievements

Past Achievements

Development of model structure of coals from Lignite to Anthracite that has been internationally accepted as Indian school of thoughts.
Categorization, reactivity and incubation period assessment of coal and lignite leading to spontaneous combustion at industrial coal-storage points and mines.
Development of method for determination of Alpha Quartz in Coal and respirable fraction of Air borne dust by FT IR spectroscopy.
Development of fly-ash based hard scouring powder.
Development of carrying-case for dust loaded membrane filters and occupationally safe dust-generating device for preparation of standards.
Development of a process for the preparation of nicotinamide from 3-cyanopyridine.

On going activities

Development of techniques for preparation of value added products including carbon nanomaterials from coal.
Development of pilot scale fluidized bed gasification facility feed rate capacity 15 - 20 kg/h and operating temperature up to 1000 oC.
Gasification of high ash (up to 50%) coals from different coal fields of India in pilot scale fluidized bed gasification facility has been accomplished successfully to study the gasification performance.
Developed correlation between physico-chemical properties of feed material and its effect on gasification kinetics.
Key contribution in the first phase of multi-feed gasification as a part of National Mission Program (NM-9) headed by DRDO for utilization of multi-feed gasifier in remote defense locations.
Developed iron and cobalt based catalysts for middle distillate and wax synthesis through FT process.
Developed three cobalt based catalysts trade named as ALCOZAR-I, II and III. which are promising to be commercial catalysts for CTL technology.
The successful installation and commissioning of the CTL Pilot Plant in a 10 L capacity reactor has been completed and tested two cobalt based CTL catalysts.

Section 2: Catalysis

Name	Designation	Email & phone
Head of the Research Group
Dr. Pashupati Dutta Briefbiodata	Sr. Principal Scientist & HORG	E-mail : pdutta[at]cimfr[dot]nic[dot]in, pdutta2002in[at]yahoo[dot]co[dot]in Phone : +91-9470121058 (M)
Section 1: Gasification Methanol and Hydrogen Economy
Dr. Prakash Dhondiram Chavan Briefbiodata	Sr. Principal Scientist & HOS	E-mail : pdchavan[at]cimfr[dot]nic[dot]in, chavanpd[at]gmail[dot]com Phone : +91-326-2388315 (O), +91 99313 13637, +91 94313 17970 (M)
Dr. Sujan Saha	Principal Scientist	E-mail : sujansaha[at]cimfr[dot]nic[dot]in, sjan_1976[at]yahoo[dot]co[dot]in Phone : +91-326-2388389 (O) , +91 94711 91168 (M)
Mr. Vishal Chauhan	Scientist	E-mail : vishalchauhan[at]cimfr[dot]nic[dot]in Phone : +91 94118 50253
Dr. Gajanan Sahu Briefbiodata	Sr. Technical Officer (1)	E-mail : gajanansahu[at]cimfr[dot]nic[dot]in, gajanansahu[at]rediffmail[dot]com Phone : +91-326-2388389, +91 99311 06448
Mr. Rakesh Kumar Rawani	Technical Assistant
Mr. Nilesh Dhananjay Dhaigude	Technical Assistant	E-mail : nddhaigude[at]gmail[dot]com, nileshdhaigude[at]cimfr[dot]nic[dot]in Phone : 7588945019 (M)
Mr. Mahendra Rajak	Salesman	E-mail : mrajak[at]cimfr[dot]nic[dot]in Phone : +91-326-2388263, +91 92045 29717
Mrs Meera Singh	Group D (NT)	Phone : +91-326-2388298, +91 72500 52720
Section 2: Catalysis
Mr. Sudipta Datta Briefbiodata	Sr. Principal Scientist & HOS	E-mail : sdatta[at]cimfr[dot]nic[dot]in, sud_datta[at]rediffmail[dot]com Phone : +91-326-2388237/389 (O), +91 9471191154 (M)
Mr. Pavan Kumar Gupta Briefbiodata	Scientist	E-mail : pavan[at]cimfr[dot]nic[dot]in, pkchehit[at]gmail[dot]com , +91-326-2388363 (O)
Mr. Shiva Kumar Saw	Technical Assistant	E-mail : shivakumar[dot]saw07[at]gmail[dot]com, shivakumar[at]cimfr[dot]nic[dot]in Phone : 7205685844 (M)
Mr. Rama Shankar Sah	Lab Assistant	E-mail : ramashankar[at]cimfr[dot]nic[dot]in Phone : 2388389

13 Results

Sl. No.	A brief description of Facilities/ Equipment/Tools/software with photos
Section 1: Gasification & Liquification
1	FTIR (Perkin Elmer) HPLC (Varian) Fluidized Bed Gasification Test Facility X-Ray Fluorescence Spectrometer (XRF) Surface Area Analyzer Thermo gravimetric Analyzer (TGA) Gas Chromatograph Fluorescence Spectrophotometer (Hitachi F-7000) Crossing Point Temperature Measurement System High Pressure Fixed Bed Tubular Reactor (Pressure-100-Bar, Temp: ~ 500^oC, Catalyst Vol-100 mL) Continuous Stirred Tank Reactor (Pressure: 100 Bar, Temp: 450 ^oC, Reactor Vol: 1.0 L) Gas Chromatograph for Gas and Liquid Analysis GC - MS TPD/TPR/Pulse Chemisorptions Unit UV-Vis Spectrometer

Sl. No.

A brief description of Facilities/ Equipment/Tools/software with photos

Section 1: Gasification & Liquification

FTIR (Perkin Elmer)

HPLC (Varian)

Fluidized Bed Gasification Test Facility

X-Ray Fluorescence Spectrometer (XRF)

Surface Area Analyzer

Thermo gravimetric Analyzer (TGA)

Gas Chromatograph

Fluorescence Spectrophotometer (Hitachi F-7000)

Crossing Point Temperature Measurement System

High Pressure Fixed Bed Tubular Reactor (Pressure-100-Bar, Temp: ~ 500^oC, Catalyst Vol-100 mL)

Continuous Stirred Tank Reactor (Pressure: 100 Bar, Temp: 450 ^oC, Reactor Vol: 1.0 L)

Gas Chromatograph for Gas and Liquid Analysis

GC - MS

TPD/TPR/Pulse Chemisorptions Unit

UV-Vis Spectrometer

Sl. No.	Name	Sponsor	Duration	Objective	Major output(if any)
Section 1: Gasification & Liquification
1	Coal Constitution (CLP 3009)	Coal Constitution		Routine analysis and tests done for outside parties and various on-going projects in this institute. Analysis and tests done are chiefly Crossing Point Temperature (CPT) and Ignition point temperature(IPT) in Coal. Quantitative determination of various functional groups in coal.	CPT and IPT of samples are determined on payment basis.
2	Prevention of asphaltene aggregation towards improving real term process viability of coal liquefaction.	SERB, DST, New Delhi	01-08-2013 to 01-08-2016	Project No - GAP–7030 To study the self aggregation phenomenon of asphaltene in molecular scale and develop an easy method in order to minimize asphaltene aggregation by trapping various guest molecules within the asphaltene aggregates for efficient conversion of coal to oil. Major outputs (if any): Coal tar samples were sourced from various nearby coke plants such as Barari, Lodna, Bhowrah etc. and also from our Coal liquefaction (CTL) plant. Coal Derived Asphaltene (CDA) sample could be successfully prepared as per ASTMD2007-80 method from respective tar samples and derived anthracene oil. The (CDA) sample was characterized by CHN, NMR, UV and Fluorescence spectroscopic analysis. Aggregation studies of CDA have been done in organic solvents with series of electron acceptors as probe materials.
3	Development of iron & cobalt based mesoporous and macroporous catalysts for conversion of syngas to liquid hydrocarbon through Fischer-Tropsch route	SERB, Department of Science and Technology, Government of India	From 16th November, 2015 to 15th November, 2018	Synthesis and characterization of iron & cobalt based mesoporous and macroporous catalysts with high surface area, tailorable pore sizes, controllable particle sizes and shapes. To determine conversion efficiency of catalysts towards syngas to liquid hydrocarbon through Fischer-Tropsch synthesis To maximize conversion efficiency and C5+ selectivity with variable reaction parameters like H2/CO ratio, space velocity, reaction temperature and pressure. To increase catalyst life and mechanical stability with different types of structural promoters (Zr, Al, B etc.) To increase thermal efficiency of the reaction and to increase syngas conversion and C5+ selectivity with doping of trace amount of reduction promoter like Ru, Pd, Pt, Cu.	Major outputs (if any): Preparation of Meso-porous support is in progress
4	Development of Indigenous Catalyst through Pilot scale studies of Coal-to-Liquid (CTL) conversion technology	Ministry of Coal, Government of India	From 1st January, 2010 to 30th June, 2016	To develop suitable catalysts and to study the coal-to-liquid conversion technology in Pilot Scale in an integrated plant consisting of low cost air blown gasifier and a multi-tubular fixed bed reactor (Catalyst Capacity: 10.0 L); To test high ash Indian coals in the gasifier; To generate basic design & process parameters for further scale-up to commercialization; To characterize the products (liquid and gaseous) and its up-gradation/processing for commercial use	Establishment of a Coal – to – Liquid Pilot Plant for testing of Fischer – Tropsch Catalysts
5	Catalytic petcoke gasification	In-house funding	September 2015 to August 2017	Selection of catalyst Gasification reactivity study with and without catalyst Effect of catalyst on petcoke conversion
6	Prefeasibility study on Coal Gasification to supplement Natural gas with Syngas (Project No. CNP-7125)	Gujarat Gas Limited, Gujarat	September 2014 to March 2016	Survey of coal Gasification Technology options available globally according to the types of coals and their pros and cons Estimated quantity and quality of coal required for running aforesaid centralized coal gasification plant on long term basis. CAPEX & OPEX of one/two selected technologies for the centralized coal gasification plant will be included in the final report. Economic analysis comparison of coal gas generated mainly from Imported coal vis-à-vis Imported natural gas.	Prepared pre-feasibility report consisting of survey of different gasification technologies and techno-economic analysis for coal to SNG project in India.
7	Tap Coal : Co-gasification of High Ash Indian Coal and Biomass (Project No:CSC-0102)	CSIR Network Project under 12th Five Year Plan	April 2013 to March 2017	Gasification Reactivity of coal-biomass blends with different gasifying agents Gasification performance of coal and coal-biomass blends in the fluidized bed gasifier (FBG) test facility Ash agglomeration behavior and entrainment during co-gasification of coal and biomass in FBG Empirical modeling of the data generated in Thermo Gravimetric Reactor (TGR), Fluidized Bed Gasifier (FBG).	Generated gasification performance database in FBG Generated gasification reactivity and kinetic data in TGA for selected coal and biomass blends.

7 Results